超高效液相色譜-三重四極桿質譜法檢測土壤農(nóng)藥殘留

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中圖分類號X833文獻標識碼A

文章編號 0517-6611（2025）15-0157-03

doi：10.3969/j. issn. 0517-6611. 2025. 15. 035 開放科學（資源服務）標識碼（OSID）：

Determination of Pesticide Residues in Soil by Ultra Performance Liquid Chromatography Triple Quadrupole MassSpectrometry HU Pei-lei，WANG Ben-long（SEP Analytical Services（Shanghai） Co.，Ltd.，Shanghai 201108）

Abstract[Objective]Ultraperformance liquidchromatography（UPLC）triplequadrupole masspectrometry（TQMS）wasestablished for thedeterminationofcarbendazim，metrbuzinandpropiconazoleresiduesinsoil.Mthod]hetargetwasextractedbyultrasound-ssistd （204號 0.1% acetonitrile-formic acid，separatedby ACQUITYUPLCBEH C18（2.1mm×100mm ， 1.7μm ），and scanned by multi-reaction monitoring（MRM）with the gradient elution using the mobile phase system of acetonitrile-0. 1% formic acid water in electrosprayed positive ionization （ESI+ ）mode.[Result]Thelinearityofthethree targets，carbendazim，metribuzinand propiconazole，was goodintherangeof 0.1- （20 （204號 100.0μg/L （ R2≥0.998 ），and the limits of detection （LODs）of the method were in the range of ，with RSD 0.33% （20 （204號 8.03% ，and the recoveries of spiking were in the range of 6 5.0%-105.0% ，and the relative standard deviations of the actual samples tested were ?4.82% .[Conclusion]Thismethodischaracterizedbyhighsensitivity，simpleoperation，lowdetectionlimit，highprecisionandaccuracy，andisitableforteteriaioofarbendaim，etrbuinndpropicoazolesiduesinsoil，hichanrovideticapport for the detection of trace pesticide residues in soil.

KeywordsUltraighperformanceliquidcomatogaphriplequadrupleasspectrometry（UPC-MS/MS）;Soil;Carbendazim;etribu zin;Propiconazole ;Pesticide residue

在現(xiàn)代農(nóng)業(yè)生產(chǎn)中，施用農(nóng)藥是保證作物增產(chǎn)增收不可或缺的生產(chǎn)要素[1]。（剩余6186字）