2</sub> 粒徑尺寸,并實現(xiàn)纖維素、 SiO<sub>2</sub> 的復(fù)合,經(jīng)冷凍干燥制得 SiO<sub>2</sub> 纖維素復(fù)合氣凝膠,用烷基硅氧烷進行疏水修飾后,制得超疏水SiO/纖維素復(fù)合氣凝膠。結(jié)果表明,纖維素氣凝膠成功與 SiO<sub>2</sub> 復(fù)合,制備的超疏水SiO2/纖維素復(fù)合氣凝膠呈現(xiàn)出多孔結(jié)構(gòu),當pH值為10時,制得的 SiO<sub>2</sub> 球體粒徑 50~200nm ,SiO/纖維素復(fù)合氣凝膠的靜態(tài)接觸角 158.9<sup>°</sup> ,滾動角 3.2<sup>°</sup> ,其吸油能力可達本身質(zhì)量的12.8倍。-龍源期刊網(wǎng)" />

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超疏水SiO2/纖維素復(fù)合氣凝膠的制備及吸油性能研究

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作者簡介:蔣松濤,工程師;主要從事綠色化學(xué)建材等方面的研究。

關(guān)鍵詞:氣凝膠;纖維素;冷凍干燥;超疏水;吸油 中圖分類號:TS721+.1 文獻標識碼:A DOI:10.11980/j.issn.0254-508X.2025.07.004

Abstract:Usingtheisolutioegenerationmetod,elloehdrogelwasprepard.Underalkalieasaatalst,edrolyse sationratoftetraeortosilcate(EO)waontrolldoregulatetesefteprepaedSiparticles,floedyhooief cellulose and SiO 2 ,which was thenfreeze-driedtoobtainaSiO/celllosecompositeaerogel.Afterhydrophobic modification withalkylsiloxane,a superhydrophobic oleophilic SiO/cellulose composite aerogel was prepared.The results indicated successful SiO incorporation into the cellulose aerogel,and the prepared SiO/celulose composite aerogel had a porous structure.At apH value of 10 ! SiO2 sphere had a size range of 5O~2O0 nm,and SiO2/cellulose composite aerogel had a static contact angle of 158.9° and a roll-off angle of 3.2° ,of which oil absorption capacity was 12.8 times its own weight.

Keywords:aerogel;cellulose;freeze-dried;superhydrophobic;oil absorption

近年來,石油泄漏問題頻發(fā),不僅造成環(huán)境污染,還危及海洋中生物的生命安全。(剩余8169字)

目錄
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