2</sub>S<sub>3</sub> 納米棒陣列表面制備一層硒氧化鉍( [Bi<sub>2</sub>0<sub>2</sub>Se] 納米片從而構(gòu)建硫化鉍/硒氧化鉍 (Bi<sub>2</sub>S<sub>3</sub>/Bi<sub>2</sub>O<sub>2</sub>Se 異質(zhì)結(jié)的方法,并研究該異質(zhì)結(jié)構(gòu)應(yīng)用于光陽極析氧反應(yīng)的情況。研究顯示,合成制備的電極材料具有優(yōu)異的單晶性能,這有助于光生載流子的傳輸?;?Bi<sub>2</sub>S<sub>3</sub>/Bi<sub>2</sub>O<sub>2</sub>Se 的異質(zhì)結(jié)的電極,其光電流密度相對于純 Bi<sub>2</sub>S<sub>3</sub> 電極和純 Bi<sub>2</sub>O<sub>2</sub>Se 電極分別提高7倍和263倍。這是由于界面處形成 Bi<sub>2</sub>S<sub>3</sub>/Bi<sub>2</sub>O<sub>2</sub>Se 的范德華異質(zhì)結(jié),極大地提高電極材料的太陽光吸收效率,同時提升光生電子-空穴對的分離效率,以及降低電子-空穴對的復(fù)合速率。-龍源期刊網(wǎng)" />

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Bi2S3/Bi2O2Se 異質(zhì)結(jié)光電極的制備與機理研究

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中圖分類號:TB332 文獻標志碼:A 文章編號:2095-2945(2025)24-0068-05

Abstract:Nanomateralshavewideaplicationpotentialinoptics,electronicsandotherfieldsduetotheiruniquesizeeffect,ich morphology,andexcelentsinglecrystalproperties.Thispaperstudiesamethodofpreparingalayerofdibismuthselenideoxide L Bi202S? e) nanosheets on the surface of a dibismuth trisulfide(F 312>: )nanorod arrayto build a dibismuth trisulfide/dibismuth selenide oxide (Bi2S/B 12O Se)heterojunction,and studiestheaplicationof thisheterostructureinthephotoanodeoxygen evolutionreactionStudies haveshownthattesthesidlectrodematerialsaveexcelentsinglecystalpropei,hichcontributestotetrasprtfpot generated carriers. The photocurrent density of the electrode based on the Bi 2S3/ Bi2OSe heterojunction is increased by 7times and 263 times compared to that of the pure Bi2S3 electrode and the pure BizO2Se electrode,respectively. This is due to the formation of a Van der Waals heterojunction of Bi2S3/B 121 OSeat the interface,which greatly improves the solar absorptionefficiency of the electrode material,improvestspatiocfotogeatedtroeiddusteobatioateoftooleis.

Keywords:heterojunction;photoelectric response;two-dimensional material; nanostructure;nanomaterials

近年來,二維層狀納米材料因其具有獨特的物理和化學(xué)性質(zhì)備受研究者的關(guān)注。(剩余5330字)

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