16</sup> ions ?cm<sup>-2</sup> 的注量注入 0.5mm 厚的 SiO<sub>2</sub> 基片中以合成所需的LSPR傳感器,再利用透射電子顯微鏡對(duì)LSPR傳感器進(jìn)行結(jié)構(gòu)表征,并借助光纖光譜儀搭建試驗(yàn)裝置,進(jìn)而實(shí)現(xiàn)LSPR傳感器的定標(biāo),以及變壓器油、石蠟油、蓖麻油、花生油、墨汁、甘油水溶液的折射率測(cè)量。結(jié)果合成的LSPR傳感器結(jié)構(gòu)穩(wěn)定,其特征反射信號(hào)的波長(zhǎng)位置線性依賴于介質(zhì)的折射率;除墨汁外,其他液體的折射率測(cè)量值均與參考值吻合;墨汁的折射率可測(cè),其值約為1.393;在甘油水溶液中,通過折射率測(cè)量得到的甘油檢出度約為 5wt% 。結(jié)論】合成的LSPR傳感器不僅能夠用于準(zhǔn)確測(cè)量透明與不透明液體的折射率,而且可以用于檢出雙組分液態(tài)混合物中的目標(biāo)物。-龍?jiān)雌诳W(wǎng)" />

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用Au離子注入 SiO2 基片合成的LSPR傳感器 測(cè)量液體折射率

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中圖分類號(hào):TB47 文獻(xiàn)標(biāo)志碼:A 文章編號(hào):1003-5168(2025)11-0079-07

DOI:10.19968/j.cnki.hnkj.1003-5168.2025.11.017

LSPR Sensor Synthesized by Au Ion Implantation into SiO2 Substrate for Liquid Refractive Index Measurement

WANG Linfei1YU Quanyin1WANG Jun2LIU Changlong3

(1.Dongying Natural Gas Processing Station,Oil-gas Gathering and Transferring General Factory,Shengli Oil

field Branch,Dongying 257Ooo,China;2.CollegeofScience,China UniversityofPetroleum(EastChina),Qingdao 266580,China; 3.School of Science,Tianjin University,Tianjin30o072, China)

Abstract: [Purposes] An attempt is made to use the localized surface plasmon resonance (LSPR) sensor prepared by implanting metal ions into transparent insulator substrate to achieve accurate measurement of the refractive index of the liquid.[Methods] The LSPR sensor is prepared by implanting 3O keV Au ions into a 0.5-mm-thick SiO substrate ata fluence of 4.5×1016 ions·cm-2 ,whose structure is charac2 terized with atransmission electron microscope.With theaid of a fiber optic spectrometer,an experimental device is built to achieve the calibration of the LSPR sensorand the measurement of the refractive indices of transformeroil,parafinoil,castoroil,peanutoil,ink,and glycerol aqueous solution.[Findings] The synthesized LSPR sensor is quite stable in structure,and its characteristic reflection signal linearly depends in wavelength position on the refractive index of medium.Except for the ink,the measured results in refractive index of other liquids are consistent with the reference values.The refractive index of theink can be measured,and the obtained result is approximately 1.393.In the glycerol aqueous solution,the glycerol detection rate obtained by refractive index measurement is approximately . [Conclusions] The synthesized LSPR sensor can be used not only for the accurate measurement of the refractive indices of transparent and opaque liquids,but also for the detection of target substance from a twocomponent liquid mixture.

Keywords: ion implantation; localized surface plasmon resonance; sensor; liquid; refractive index

0 引言

折射率是物質(zhì)的固有屬性之一。(剩余12430字)

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